Lost in Time is a DVD boxed set of collected "orphan" episodes and related clips from Doctor Who, specifically from the first two Doctors. I borrowed this recently and was surprised to find a couple of short DID scenes:
The best one occurs right at the start - in the first episode of The Crusade Barbara is handgagged, then her wrists are tied behind her with dark-colored rope and she's given an OTM cloth gag. (Well, I suppose the Saracens wouldn't have had duct tape ...)
In The Underwater Menace Polly has her wrists tied in front with what appears to be a vine.
In The Faceless Ones Polly is handgagged by an alien in human guise but is not otherwise restrained - a great opportunity wasted.
(I thought there were three handgaggings, but if so I find I can't recall it. I watched three disks in a short period, and after a while all these old black-and-white Doctor Who episodes started to blur together.)
Doctor Who: Lost in Time
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Re: Doctor Who: Lost in Time
Polly also has a scene in the smugglers however it a lost episode meaning we might never again see it its on audio through